Want To Know The Difference of Zinc Plating, Cadmium, Chromium and Nickel?
Zinc Plating:
Zinc is relatively stable in dry air and is
not easy to change color. In water and humid atmosphere, it reacts with oxygen
or carbon dioxide to form oxide or alkaline zinc carbonate film, which can
prevent the zinc from continuing to be oxidized and play a protective role.
Zinc is easily corroded in acids, alkalis,
and sulfides. The galvanized layer generally needs to be passivating treated.
After passivation in chromic acid or chromate solution, the formed film is not
easy to interact with humid air, and the anti-corrosion ability is greatly
enhanced.
Advantages: low cost, convenient processing,
and good effect.
Application: commonly used in atmospheric
conditions and other good environments. But not suitable for friction parts
Cadmium plating:
Cadmium coating is softer than zinc
coating, it has less hydrogen embrittlement and strong adhesion; under certain
electrolytic conditions, the obtained cadmium coating is more beautiful than
the zinc coating. But the gas produced when cadmium melts is poisonous, and
soluble cadmium salts are also poisonous.
Application: mainly used to protect parts from
the atmospheric corrosion of sea water or similar salt solutions and saturated
sea water vapor. Many aviation, marine and electronic industrial parts,
springs, and threaded parts use cadmium plating. Can be polished, phosphated and used as
a primer, but cannot be used to food wares.
Chromium plating:
very stable in humid atmosphere, alkali,
nitric acid, sulfide, carbonate solutions and organic acids, and is easily
soluble in hydrochloric acid and hot concentrated sulfuric acid.
The chromium layer has strong adhesion,
high hardness, 800~1000V, good resistance, strong light reflectivity, and high
heat resistance. It does not change color below 480℃, starts to
oxidize above 500℃, at 700℃ hardness decreased significantly. The disadvantage of chromium is hard,
brittle, and easy to fall off, which is more obvious when subjected to
alternating impact loads.
Application: it’s not suggested to do chromium
plating singly as an anti-corrosion layer. Generally, multi-layer
electroplating (ie copper plating → nickel → chromium)
can achieve the purpose of rust prevention and decoration. At present, it is
widely used to improve the abrasive resistance of parts, repair size, light
reflection and decorative lights.
Nickel plating:
Nickel has good chemical stability in the
atmosphere and lye, and not easy to change color. It will be oxidized only when
the temperature is above 600°C. It dissolves very slowly in sulfuric acid and
hydrochloric acid, but easily soluble in dilute nitric acid. It is easy to
passivate in concentrated nitric acid therefore has good corrosion resistance.
The nickel coating has high hardness, easy
to be polished, has high light reflectivity so it looks bright. The
disadvantage is that it has porosity. So it’s suggested to do a multilayer
metal coating, nickel to be the intermediate layer.
Application: Usually in order to prevent
corrosion and get good looking, it is generally used to protect decorative
coatings. Nickel plating on copper products is ideal for anticorrosion, but
because nickel is more expensive, copper-tin alloy plating is often used
instead of nickel plating.